应用研究

极地用隔热耐磨涂层的制备及性能研究

  • 方赵文 ,
  • 许 吉 ,
  • 朱能杰 ,
  • 楼晨铱 ,
  • 熊梦瑶 ,
  • 蓝席建
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  • 1. 宁波大学材料科学与化学工程学院,浙江宁波315211;

    2. 中国科学院宁波材料技术与工程研究所海洋关键材料全国重点实验室,浙江宁波315201

网络出版日期: 2026-04-27

基金资助

国家自然科学基金( 52425501)

Preparation and Performance of Thermal Insulating and Wear-resistant Coating for Polar Applications

  • FANG Zhaowen ,
  • XU Ji ,
  • ZHU Nengjie ,
  • LOU Chenyi ,
  • XIONG Mengyao ,
  • LAN Xijian
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  • 1. School of Materials Science and Chemical Engineering,Ningbo University,Ningbo,Zhejiang 315211,China;

    2. State Key Laboratory of Advanced Marine Materials,Ningbo Institute of Materials Technology & Engineering,Chinese Academy of Sciences,Ningbo,Zhejiang 315201,China

Online published: 2026-04-27

摘要

【目的】解决极地海洋环境下聚甲基丙烯酸甲酯( PMMA)盖板面临的低温侵袭与浮冰碰擦对某装备运行造成的障碍。【方法】开发了环氧 -低导热 -高附着的隔热底漆和聚硅氧烷 -高耐磨 -防碰擦面漆所构成的双层复合涂层体系。【结果】面漆在 .35 ℃,500 g/(1 000 r)下磨损质量为 64. 5 mg,同时配套涂层体系在经受 .30 ℃浮冰冲击试验后保持表面完整,并具备优异的耐盐雾性与耐老化性。此外,本体系使 PMMA盖板导热系数从 0. 141 W/(m·K)降至 0. 108 W/(m·K),底漆导热系数低至 0. 049 W/(m·K)。 -55 ℃低温环境下,将单面涂覆复合涂层和空白的 PMMA样板分别作为绝热箱盖板,常温下贴敷密封后静置 60 min,二者内部温差达 10. 61 ℃,满足装备服役需求。【结论】该涂层体系以零能耗方式同步实现了有效隔热、低温耐磨、耐浮冰碰擦与良好的耐候性,为极地装备在低温、高盐、浮冰等多因素耦合环境下的高可靠防护提供了可行的解决方案。

本文引用格式

方赵文 , 许 吉 , 朱能杰 , 楼晨铱 , 熊梦瑶 , 蓝席建 . 极地用隔热耐磨涂层的制备及性能研究[J]. 涂料工业, 2026 , 56(5) : 47 -53 . DOI: 10.12020/j.issn.0253-4312.2025-340

Abstract

[Objective] To address the operational challenges faced by PMMA cover plates in polar marine environments,including low-temperature intrusion and floating ice collision in polar marine environment.[Methods]A dual-layer composite coating system was developed,consisting ofan epoxy-based thermal insulation primer with low thermal conductivity and high adhesion,and a polysiloxane-based topcoat with high wear resistance and impact protection.[Results]The topcoat exhibited a wear value of 64. 5 mg at -35 ℃ under 500 g/1 000 r. Meanwhile,the coating system maintained surface integrity after undergoing -30 ℃ ice impact testing while demonstrating excellentsalt spray resistance and weather resistance. Additionally,this system reduced the thermal conductivity of PMMA covers from 0. 141 W/(m·K) to 0.108W/(m·K), while the thermal conductivity of the primer was as low as 0. 049 W/(m·K). In a -55 ℃ low-temperature environment,coated and uncoated PMMA samples were used as insulation box covers. After sealing at room temperature and resting for60 minutes,the internal temperature difference between them reached 10. 61 ℃,meeting equipment service requirements.[Conclusion] This coating system simultaneously achieves effective thermal insulation,low-temperature wear resistance,resistance to floating ice impact,and excellent weather resistance in an energy-neutral manner. It provides a viable solution for high-reliability protection ofpolar equipment in environments characterized by the coupled effects of low temperatures,high salinity, and floating ice.
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