探索开发

纳米纤维素改性BIT-丙烯酸酯类海洋防污涂料的合成及降解性能研究

  • 朱 萌 ,
  • 张馨元 ,
  • 董 苗 ,
  • 刘欣仪 ,
  • 徐小栋 ,
  • 林心蕊 ,
  • 陈俊华 ,
  • 杨建新 ,
  • 薛行华
展开
  • 1. 海南大学环境科学与工程学院,海口570228;

    2. 海南大学化学化工学院,海口市绿色催化与反应工程重点实验室,海口570228

杨建新(1971—),男,博士,教授,主要从事精细化学品分子设计与合成和有机功能材料的研究;邮箱: yangjxmail@sohu.com。
薛行华(1973—),男,博士,教授,主要研究方向为精细化学品设计与合成、海洋功能高分子材料;邮箱: xxh408@163.com。

网络出版日期: 2025-11-05

基金资助

海南省自然科学基金项目( 425MS040);国家自然科学基金项目(52063011)

Synthesis and Degradation Performance Study of Nano-cellulose-modified BIT-acrylate Marine Antifouling Coatings

  • ZHU Meng ,
  • ZHANG Xinyuan ,
  • DONG Miao ,
  • LIU Xinyi ,
  • XU Xiaodong ,
  • LIN Xinrui ,
  • CHEN Junhua ,
  • YANG Jianxin ,
  • XUE Xinghua
Expand
  • 1. School of Environmental Science and Engineering,Hainan University,Haikou 570228,China;

    2. Key Laboratory of Green Catalysis and Reaction Engineering of Haikou,School of Chemstry and Chemical Engineering,Hainan University,Haikou 570228,China

Online published: 2025-11-05

摘要

【目的】丙烯酸酯类树脂虽为当前海洋防污涂料的主流基料,但其降解性能差,存在潜在海洋环境累积风险,需提高丙烯酸酯类海洋防污涂料的降解性能。【方法】将纳米纤维素与接枝 1,2-苯并异噻唑 .3-酮(BIT)的丙烯酸酯树脂进行物理共混,成功制备出一系列具有优异降解性能的海洋防污涂料。利用红外光谱对树脂结构进行表征,并测试该涂层在海水环境与土壤环境中 6个月的降解率,通过水接触角评估该涂层亲水性,采用抑藻测试与浅海挂板测试验证该涂料的防污性能。【结果】该系列涂料在海水和土壤环境中均表现出良好的降解性能。在海水浸泡后涂层的水接触角呈现明显下降趋势,且纳米纤维素含量越高的涂层下降幅度越大。该涂层对 2种典型海洋藻类小球藻和金褐藻的生长均具有显著的抑制作用,其中对金褐藻的抑制效果较为突出;浅海挂板实验表明所制备的涂料具有较好的防污性能。【结论】纳米纤维素共混改性的丙烯酸树脂,不仅展现出了良好的生物降解特性,而且保持了其防污能力,在海洋防污涂料领域具有潜在的应用前景。

本文引用格式

朱 萌 , 张馨元 , 董 苗 , 刘欣仪 , 徐小栋 , 林心蕊 , 陈俊华 , 杨建新 , 薛行华 . 纳米纤维素改性BIT-丙烯酸酯类海洋防污涂料的合成及降解性能研究[J]. 涂料工业, 2026 , 56(2) : 13 -19 . DOI: 10.12020/j.issn.0253-4312.2025-262

Abstract

[Objective] Acrylic resins are the primary binders in current marine antifouling coatings,but their poor degradability poses a potential risk of accumulation in the marine environment.It is necessary to improve the degradation performance of acrylic-based marine antifouling coatings.[Methods] A series of marine antifouling coatings with excellent degradability were successfullyprepared by physically blending nanocellulose with acrylic resin grafted with 1,2-benzisothiazolin-3-one(BIT). The resin structure was systematically characterized using infrared spectroscopy. The degradation rates of the coating were measured over 6 months in seawater and soil environments. Thehydrophilicity of the coating was evaluated via water contact angle measurement,and the antifoulingperformance was verified through algal inhibition tests and shallow-sea panel tests.[Results] The coatings demonstrated excellent degradation performance in both seawater and soil environments. Afterseawater immersion,the water contact angle of these coatings decreased significantly,with a more pronounced reduction observed for coatings containing higher nanocellulose content. The coatings significantly inhibited the growth of two typical marine algae,Chlorella and golden-brown algae,with particularly pronounced inhibition against golden-brown algae. Shallow-sea panel experiments demonstrated that the prepared coatings possess good antifouling performance.[Conclusion]Acrylicresins modified by blending with nanocellulose not only exhibited excellent biodegradability but alsoretained their antifouling properties,demonstrating potential application prospects in the field of marine antifouling coatings.
文章导航

/