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苯并异噻唑啉酮-乙酸铜树脂的制备及其防污性能研究

  • 盛宏伟 ,
  • 刘欣仪 ,
  • 董 苗 ,
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  • 海南大学化学化工学院,海口市绿色催化与反应工程重点实验室,海口570228

陈俊华( 1979—),女,硕士,讲师,主要从事绿色催化和合成;邮箱: klchjh@126.com;

杨建新( 1971—),男,博士,教授,主要从事精细化学品分子设计与合成和有机功能材料的研究;邮箱: yangjxmail@sohu.com。


网络出版日期: 2025-09-17

基金资助

海南省自然科学基金项目( 522MS040,425MS040);国家自然科学基金项目( 52063011) 

Preparation and Antifouling Properties of Benzisothiazolinone-copper Acetate Resin

  • SHENG H W ,
  • LIU X Y ,
  • DONG M ,
  • et al
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  • Key Laboratory of Green Catalysis and Reaction Engineering of Haikou,School of Chemistry and Chemical Engineering,Hainan University,Haikou 570228,China

Online published: 2025-09-17

摘要

【目的】本研究旨在制备具有高效海洋防污性能的新型树脂材料。【方法】创新性地将异噻唑啉酮类化合物 1,2-苯并异噻唑-3-酮( BIT)与铜类化合物结合,成功制备新型含铜功能性单体( BIT-乙酸铜)。随后通过自由基聚合反应,将不同含量的 BIT-乙酸铜接入丙烯酸树脂侧链,得到新型 BIT-乙酸铜树脂。采用核磁共振波谱仪和傅立叶变换红外光谱仪( FT-IR)对合成的单体和树脂进行结构表征,并通过抑藻、抑菌测试和 60 d实海挂板测试评价其防污性能。【结果】 BIT-乙酸铜树脂对 3种藻类和 2种细菌均展现出优异抑制性,抑藻率最高达 80%,抑菌率接近 100%。60 d的实海挂板测试表明树脂具有良好的实海防污性能,且当 BIT-乙酸铜含量在 10%左右时,污损生物抑制效果最佳,同时涂层表面无开裂或脱落现象。【结论】制备的 BIT-乙酸铜树脂兼具高效海洋防污性能与稳定的力学性能。

本文引用格式

盛宏伟 , 刘欣仪 , 董 苗 , . 苯并异噻唑啉酮-乙酸铜树脂的制备及其防污性能研究[J]. 涂料工业, 2025 , 55(10) : 17 -22 . DOI: 10.12020/j.issn.0253-4312.2025-198

Abstract

[Objective] This study aimed to develop a new resin material combining efficientmarine antifouling performance with stable mechanical properties.[Methods] A novel copper-containing functional monomer(BIT-copper acetate)was prepared by innovatively combining 1,2-benzisothiazol-3-one(BIT)with a copper compound. Subsequently,through free radical polymerization, the monomer was then grafted at varying contents onto the side chain of acrylic resin to prepare the newBIT-copper acetate resin. The structures of the synthesized monomer and resin were characterizedusing 1H NMR and FT-IR spectroscopy. The antifouling performance was evaluated by algae andbacterial inhibition tests as well as a 60-day real-sea hanging plate test.[Results]The resin exhibited excellent inhibitory effects against three species of algae and two species of bacteria,with a maximum algae inhibition rate of 80% and a bacteriostasis rate close to 100%. The 60-day real-sea hanging plate test confirmed its good antifouling performance in a real marine environment. The optimal foulinginhibition was achieved when the BIT-copper acetate content was around 10%,and no cracking or peeling was observed on the coating surface.[Conclusion]The prepared BIT-copper acetate resindemonstrated both high antifouling efficiency and stable mechanical properties.
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