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复配金属氧化物/硅溶胶耐高温防腐涂层研究

  • 张总宣 ,
  • 陈 洋 ,
  • 雪 伟 ,
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  • 1. 天津大学浙江研究院(绍兴),浙江绍兴312300;

    2. 德阳和新环保发电有限责任公司,四川德阳618000;

    3. 浙江诺泰电力工程有限公司,浙江湖州 313100;

    4. 天津大学化工学院,天津300072;

    5. 诺丁汉大学卓越灯塔计划(宁波)创新研究院,浙江宁波315100

张总宣(1992—),男,博士,主要从事功能涂料的研究。
陈洋( 1975—),男,本科,工程师,主要从事垃圾发电、火力发电项目生产运行及工程建设;邮箱: hzdccy@163.com。
张海萍( 1982—),女,博士,副教授,主要从事功能涂料的研究;邮箱: hpzhang@tju.edu.cn。

网络出版日期: 2025-07-31

基金资助

企业合作项目( DYHB-1-CFW-2024-023);佛山市科技创新项目(1920001000150-08)

Study on High-temperature-resistant and Anticorrosive Coatings of Composite Metal Oxides/Silica Sol

  • ZHANG Z X ,
  • CHEN Y ,
  • XUE W ,
  • et al
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  • 1. Zhejiang Institute of Tianjin University,Shaoxing,Zhejiang 312300,China;

    2. Deyang Hexin Environmental Power Generation Co., Ltd., Deyang,Sichuan 618000,China;

    3. Zhejiang Nuotai Electric Power Engineering Co., Ltd., Huzhou,Zhejiang 313100,China;

    4. School of Chemical Engineering and Technology,Tianjin University,Tianjin 300072,China;

    5. Nottingham Ningbo China Beacons of Excellence Research and Innovation Institute,Ningbo,Zhejiang 315100,China

Online published: 2025-07-31

摘要

【目的】解决传统垃圾焚烧锅炉防护涂料高温耐受性不足、耐腐蚀性差等问题。【方法】开发了一种基于复配金属氧化物与改性硅溶胶的协同作用的新型抗结焦防腐涂层。采用扫描电子显微镜( SEM)、 X射线衍射仪( XRD)及傅立叶变换红外光谱仪( FT-IR)对涂层结构进行表征。采用铅笔硬度、落锤冲击、高温烧结和盐雾腐蚀试验研究了涂层的综合性能。【结果】涂层的铅笔硬度达到 4H,耐冲击性为 63 cm,耐 1 800 ℃烧结, 39 d的盐雾试验涂层不受影响。【结论】复配金属氧化物与改性硅溶胶能显著改善涂层的抗结焦防腐性能。

本文引用格式

张总宣 , 陈 洋 , 雪 伟 , . 复配金属氧化物/硅溶胶耐高温防腐涂层研究[J]. 涂料工业, 2025 , 55(8) : 14 -17 . DOI: 10.12020/j.issn.0253-4312.2025-112

Abstract

[Objective]To address the issues of insufficient high-temperature resistance and poorcorrosion resistance of traditional protective coatings for waste incineration boilers.[Methods]A new type of anti-coking and anticorrosive coating was developed based on the synergistic effect of hybridmetal oxides and modified silica sol-gel. The coating structure was characterized by Scanning ElectronMicroscopy(SEM), X-ray Diffractometer(XRD), and Fourier Transform Infrared Spectrometer(FT-IR). The comprehensive performance of the coating was investigated by pencil hardness testing,drop-weight impact testing,high-temperature sintering and salt spray corrosion tests.[Results]The pencil hardness of the coating reached 4H,the impact resistance was 63 cm,and it could withstand sintering at 1 800 ℃. The coating was not affected in the 39-day salt spray test.[Conclusion]Hybridmetal oxides combined with modified silica sol-gel can significantly improve the anti-coking andanticorrosive performance of the coating. 
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