工艺技术

颜填料和膨胀防火助剂对无机膨胀型防火涂料性能的影响

  • 关志会 ,
  • 张志勇 ,
  • 曹立刚 ,
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  • 1.南昌大学物理与材料学院,南昌 330031;
    2.山东兖州建设总公司,山东济宁 272100
杜国平( 1967—),男,教授,博士生导师,从事涂料、陶瓷及能源材料方面的研究与产品开发工作。

网络出版日期: 2024-11-01

基金资助

山东省工信厅技术创新项目( 202350800363、202250800582)

Effect of Pigments and Intumescent Fire Retardants on the Performance of Inorganic Intumescent Fire Retardant Coatings

  • GUAN Z H ,
  • ZHANG Z Y ,
  • CAO LG ,
  • et al
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  • 1.School of Physics and Materials Science,Nanchang University,Nanchang 330031,China;

    2.Shandong Yanzhou Construction Corporation,Jining,Shandong 272100,China

Online published: 2024-11-01

摘要

以硅酸钾溶液和苯丙乳液作为成膜剂,通过控制颜填料和膨胀防火助剂的添加量,以提高无机膨胀型防火涂料的理化性能和防火性能,且通过热重( TG-DTG)、X射线衍射(XRD)、红外光谱(FT-IR)分析涂层的防火机理。结果表明:制备无机膨胀型防火涂料的最佳工艺参数是以 5%的滑石粉、 4%的钛白粉和 6%玻璃粉作为颜填料,膨胀防火助剂白云石、氢氧化铝和可膨胀石墨添加量分别为 5%、20%、2%。涂层防火性能测试后质量损失仅 36. 87%,且形成了新的陶瓷相。涂层在耐火 1h后,其背板最高温度为 286 ℃,灼烧后可膨胀 9. 2倍左右,极大地提升了硅酸钾无机膨胀型防火涂料的理化性能和防火性能。

本文引用格式

关志会 , 张志勇 , 曹立刚 , . 颜填料和膨胀防火助剂对无机膨胀型防火涂料性能的影响[J]. 涂料工业, 2024 , 54(11) : 23 -29 . DOI: 10.12020/j.issn.0253-4312.2024-154

Abstract

Potassium silicate solution and styrene-acrylic emulsion were used as film-forming agents. The physicochemical and fireproof properties of the inorganic fire-retardantcoatings were improved by controlling the amount of pigment fillers and fire retardants. Andthe coating fire protection mechanism was analyzed by TG-DTG,XRD and FT-IR. The results showed that the optimal process parameters for the preparation of potassium silicate inorganicfire-retardant coatings were 5% talc powder,4% titanium dioxide and 6% glass powder as pigment fillers,5% dolomite,20% aluminum hydroxide and 2% expandable graphite as fireretardants. The results of TG-DTG,XRD and FT-IR showed that the mass loss of coating was 36. 87% before and after fire protection and a new ceramic phase was formed. After 1 h of fireresistance of the coating,the maximum temperature of the back plate was 286℃,and the coating could be expanded about 9. 2 times after burning. The physicochemical and fireproofproperties of potassium silicate inorganic fire-retardant coatings were greatly improved.
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