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超疏水防紫外双功能水性织物涂层的制备及性能研究

  • 王雪梅 ,
  • 车晓刚 ,
  • 李勇迪 ,
  • 安滔 ,
  • 赵若伊 ,
  • 刘景艳 ,
  • 陈坤林 ,
  • 王潮霞
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  • 生态纺织教育部重点实验室,江南大学纺织服装学院,江苏无锡,214122

收稿日期: 2019-03-18

  修回日期: 2019-07-09

  网络出版日期: 2019-09-01

基金资助

江南大学国家级大学生创新创业训练计划;江苏省自然科学基金;博士后基金

Fabrication and Properties of Waterborne Dual Functional Fabric Coatings with Superhydrophobicity and UV Protection

  • WANG Xue-Mei ,
  • CHE Xiao-Gang ,
  • LI Yong-Di ,
  • AN Tao ,
  • DIAO Ruo-Yi ,
  • LIU Ying-Yan ,
  • CHEN Kun-Lin ,
  • WANG Chao-Xia
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  • Key Laboratory of Eco-textile,Ministry of Education,College of Textiles & Clothing,Jiangnan University,Wuxi, Jiangsu 214122,China

Received date: 2019-03-18

  Revised date: 2019-07-09

  Online published: 2019-09-01

摘要

利用乳液缩聚法制备芯材为氟硅烷( FAS13)壁材接枝紫外吸收剂的二氧化硅微胶囊,将其与有机硅树脂乳液共混,涂覆于棉织物表面形成超疏水防紫外织物涂层。通过扫描电镜和透射电镜观察微胶囊的形态和粒径,并对涂层的水接触角和防紫外性能进行了测试,同时测试了涂层的耐老化、耐磨损、耐高温以及耐酸碱性。结果表明:织物涂层中微胶囊最佳含量为 45%(其中内含 6%紫外吸收剂),由此制备的涂层表面水接触角可达到 150°以上,并且具有较好的耐老化、耐高温、耐酸碱腐蚀、耐磨损等性能;同时该织物涂层具有优异的防紫外性,紫外线防护系数(UPF)可以达到 111.2。

本文引用格式

王雪梅 , 车晓刚 , 李勇迪 , 安滔 , 赵若伊 , 刘景艳 , 陈坤林 , 王潮霞 . 超疏水防紫外双功能水性织物涂层的制备及性能研究[J]. 涂料工业, 2019 , 49(9) : 1 -6 . DOI: 10.12020/j.issn.0253-4312.2019.9.1

Abstract

Silicon dioxide microcapsules with fluorosilane(FAS13)as core material and silicon dioxide grafted with ultraviolet absorbent as shell were prepared by emulsion condensation polymerization. The microcapsules were blended with silicone latex,which was coated on the surface of cotton fabric to obtain a superhydrophobic and UV protective fabric coatings. The morphology and particle size of microcapsules were observed by SEM and TEM,and the water contact angle and UV protection performance of fabric coatings was tested. In the meantime,the weather resistance,wear resistance,high temperature resistance and acid and alkali resistance of coatings were also measured. The results showed that the best percentage of the microcapsules in fabric coatings was 45%(incorporated with 5% UV absobent),and the water contact angle of the prepared coating surface could reach higher than 150° . Moreover,the obtained fabric coatings provided good weather resistance,high temperature resistance,acid and alkali resistance and wear resistance. At the same time,the ultraviolet protection factor(UPF)of the fabric coatings could reach 111. 2,which showed excellent UV resistance.

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