随着高分子合成技术的迅速发展，乳液聚合法的发展创新趋势较为明显，其聚合过程对商品聚合物的生产至关重要，所制备出的聚合物乳液可直接用作水性涂料和胶粘剂等。文中具体介绍了细乳液聚合体系的设计方法、聚合过程及稳定机理，重点综述了近年来细乳液聚合在高固含量细乳液制备、纳米复合材料制备（荧光聚合物纳米粒子、有机 /无机纳米复合材料）及聚合物空心球或微球制备等方面的研究进展。
With the rapid development of polymer synthesis technology，the development trend of emulsion polymerization is more obvious. Now its polymerization process is more important for the production of commercial available polymers.The emulsion can be directly used for waterborne coatings and adhesives，etc. The preparation technique，polymerization process and stabilization mechanism of mini-emulsion polymerization system were introduced in this paper，focusing on the recent progress of minie-emulsion polymerization in the preparation of high solid content polymer mini-emulsion，nanocomposite（fluorescent polymer nanoparticles，organic / inorganic nanocomposites） and hollow or microspheres polymer was reviewed in this paper.
[1]UGELSTAD J，EL-AASSER M S，VANDERHOFF J W.Emulsion polymerization：Initiation of polymerization inmonomer droplets[J].Journal of Polymer Science Part APolymer Chemistry, 2010, 11(8):503-513
[2]张建军 .通过细乳液聚合和原子转移自由基聚合制备杂化纳米粒子及其性质研究 [D].长春：吉林大学， 2011： 18-20.
[3]何翠莲 .通过活性聚合方法设计合成新型嵌段聚合物的研究 [D].青岛：青岛大学， 2007：16-17.
[4]李晶晶，樊江莉，彭孝军.基于细乳液聚合的纳米颗粒制备与应用研究进展[J].应用化学, 2018, 35(9):1026-1036
[5]JOSE M，ASUA. Ostwald ripening of reactive costabilizers in miniemulsion polymerization[J].[J].European Polymer Journal, 2018, 106:30-41
[6]武鹏，桑晓明，于守武，等.细乳液聚合的研究进展[J].塑料工业, 2011, 38(S1):1-5
[7]WANGZH，QIU T，GUO L H，et al. The building of molecularly imprinted single hole hollow particles：A miniemulsion polymerization approach[J].[J].Chemical Enginee-ring Journal, 2019, 357:348-357
[8]高强 .细乳液聚合制备 PAN纳米粒子及其机理 [D].广州：华南理工大学， 2015：8-10.
[9]相东旭，黄建群，何文栋 .高固含量低黏度聚合物乳液的研究进展 [J].涂料工业， 2016，46（11）81-85.
[10]RONCO L I，MINARI R J，MEIRA G Rt al. Toughened polystyrene nanoparticles through high-solids miniemulsion polymerization[J].[J].Chemical Engineering Journal, 2015, 263:231-238
[11]高党鸽，梁志扬，吕斌，等.细乳液聚合法制备高固含量聚丙烯酸酯乳液及性能[J].精细化工, 2016, (10):1125-1129
[12]AIZQ，DENG R，ZHOU Q L，et al.High solid content latex：Preparation methods and application[J].Advances inColloid and Interface Science, 2014, 159(1):45-59
[13] HERK A M.Chemistry and technology of emulsion polymeri-zation[M]. Oxford：Blackwell Publishing Ltd，2011：42.
[14]EL-GHAFFAR M A，SHERIF M H，EI-HABAB A T. Novel high solid content Nano Siliconated polyTerpolymer latex for high performance latex paints[J].[J].Chemical Engineering Journal, 2016, 301:285-298
[15]LIANG R X，ZHANG P P，WEI C Q，et al. Spontaneousformation of bimodal particle size distributions：A novel one-step strategy for obtaining high solid content，low viscosity poly latexes[J].[J].Progress in Organic Coatings, 2017, 110:86-96
[16]LEIZA，EDURNE G，AUDREY B F，et al. Photoactive self-cleaning polymer coatings by TiO2 nanoparticle Pickering miniemulsion polymerization[J].[J].Chemical Engineering Journal, 2015, 281:209-217
[17]GUYOT A，CHU F，SCHNEIDER M，et al.High solid contentlatexes[J].Progress in Polymer Science, 2002, 27(8):1573-1615
[18]许冰文，孙彦琳 .二元分布高固含量聚丙烯酸酯乳液的制备 [D].昆明：昆明理工大学， 2015（5）：1-70.
[19]AIZPURUA I，AMALVY J I，BARANDIARAN M J.Highsolids content miniemulsion polymerization of vinyl acetate in acontinuous stirred tank reactor[J].Polymer, 2001, 42(4):1417-1427
[20]丁秋炜，徐俊英，滕大勇.高分子表面活性剂对细乳液聚合的影响[J].天津化工, 2014, 25(5):1-4
[21]WANG Z H，QIU T，GUO L H，et al. The synthesis of molecularrecognition polymer particles via miniemulsion polymeri-zation[J].[J].Reactiveand FunctionalPolymers, 2018, 126:1-8
[22]黄富华，陈建，李亚，等.细乳液聚合制备新型红色荧光聚合物纳米粒子[J].胶体与聚合物, 2014, 32(1):6-9
[23]ZHAO Y M，ZHU W，REN L X，et al.Aggregation-inducedemission polymer nano-particles with pH-responsive fluores-cence[J].Polymer Chemistry, 2016, 7(34):5386-5395
[24]YANLL，ZHANG Y，XU B，et al.Fluorescent nanoparti-cles based on AIE fluorogens for bioimaging[J].Nanoscale, 2016, 8(5):2471-2487
[25]XUSY，BAI X L，MA J W，et al.Ultrasmall organic nanoparticles with aggregation-induced emission and enhanced quantum yield for fluorescence cell imaging[J].Analytical Chemistry, 2016, 88(15):7853-7857
[26]LIANG X Q，HU Y X，LOU J J，et al. Mechanistic investigationon fluorescence instability of AIE polymeric nanoparticleswith a susceptible AIEgen prepared in miniemulsions[J].[J].Dyes and Pigments, 2019, 160:572-578
[27]TANIGUCHI T，TAKEUCHI N，KOBARU S，et al.Preparation of highly monodisperse fluorescent polymerparticles by miniemulsion polymerization of styrene with apolymerizable surfactant[J].Journal of Colloid and InterfaceScience, 2011, 327(1):58-62
[28]ANDO K，KAWAGUCHI H.High-performance fluorescent particles prepared via miniemulsion polymerization[J].Journal of Colloid and Interface Science, 2015, 285(2):619-626
[29]BHANVASE B A，SONAWANE S H. Ultrasound assisted in situ emulsion polymerization for polymer nanocomposite：A review[J].[J].Chemical Engineering＆ Processing Process Intensification, 2014, 85:86-107
[30]WANG W N，MENG Z，ZHANG Q H，et al. Synthesis of stable Au-SiO2 composite nanospheres with good catalyticactivity and SERS effect[J].[J].Journal of Colloid and InterfaceScience, 2014, 418:1-7
[31]LEE J，PARK J C，SONG H.A nanoreactor framework of a Au@SiO2 yolkshell structure for catalytic reduction of p-nitro-phenol[J].Advanced Materials, 2011, 20(8):1523-1528
[32]KIM M，PARK J C，KIM A，et al.Porosity control of Pd@SiO2 yolk-shell nanocatalysts by the formation ofnickel phyllosilicate and its influence on Suzuki couplingreactions[J].Langmuir, 2014, 28(15):6441-6447
[33]YAO J，CAO Z H，SHANG Y，et al. Preparation of polyme-ricinorganic nanocomposite particles in miniemulsions：II. Narrowly size-distributed polymer SiO2 nanocomposite particles[J].[J].Colloids and Surfaces A, 2017, 530:104-116
[34]CAO Z H，CHEN H G，ZHU S D，et al. Inverse miniemulsion-based preparation of raspberry-like AuSiO2 nanocomposite particles with high catalytic activity towardsreduction of p-nitrophenol[J].[J].Colloids and Surfaces A-Physicochemical and Engineering Aspects, 2016, 489:223-233
[35]WUYF，ZHANG Y，XU J X，et al.One-step preparation of PSTiO2 nanocomposite particles via miniemulsion polymeri-zation[J].Journal of Colloid and Interface Science, 2014, 343(1):18-24
[36]GAURAV K U，JEEVITESH K R，TRILOK K P，et al. Synthesis of ZnO：TiO2 nanocomposites for photocatalystapplication in visible light[J].[J].Vacuum, 2019, 160:154-163
[37]ZHUBD，ZHOU Q，ZHEN D S，et al. Preparation of TiO2 Bi Fe Zr nanocomposite for the highly selectiveenrichment of phosphopeptides[J].[J].Talanta, 2019, 194:870-875
[38]MANIBALAN G，MURUGADOSS G，THANGAMUTHU R， et al. Facile synthesis of heterostructure CeO2-TiO2 nanocom-posites for enhanced electrochemical sensor and solar cellapplications[J].[J].Journal of Alloys and Compounds, 2019, 773:449-461
[39]WANG H，WANG R X，WANG L，et al.Preparation of multi-coresingle-shell OA-Fe3O4PANI bifunctional nanopar-ticles via miniemulsion polymerization[J].Colloids and Surfaces A -Physicochemical and Engineering Aspects, 2014, 384(1-3):624-629
[40]DOUJB，ZHANG Q Y，MA M L，et al.Fast fabrication of epoxy-functionalized magnetic polymer core-shell microsp-heres using glycidyl methacrylate as monomer via photo-initiated miniemulsion polymerization[J].Journal of Magnetismand Magnetic Materials, 2014, 324(19):3078-3082
[41]SUN Y，WANG B，WANG H P，et al.Controllable preparation of magnetic polymer microspheres with differentmorphologies by miniemulsion polymerization[J].Journal ofColloid and Interface Science, 2014, 308(2):332-336
[42]ZHANG J J，GAO G，ZHANG M，et al.ZnOPS core-shellhybrid microspheres prepared with miniemulsion polymeriza-tion[J].Journal of Colloid and Interface Science, 2016, 301(1):78-84
[43]ZHANG N，HU X L，GUAN P，et al. Preparation of proteinimprinted microspheres using amphiphilic ionic liquid asstabilizer and emulsifier via miniemulsion polymerization[J].[J].Chemical Engineering Journal, 2017, 317:356-367
