健康·安全·环境

石膏饰面层对聚苯乙烯板耐火性能影响

  • 于水军 ,
  • 杨岱霖 ,
  • 魏月贝 ,
  • 谢高超
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  • 1.河南理工大学安全科学与工程学院,河南焦作 454003; 2.煤炭安全生产河南省协同创新中心,河南焦作 454003; 3.河南省煤矿瓦斯与火灾防治重点实验室,河南焦作 454003
于水军(1962—),男,教授,研究方向为火灾防治理论与技术。

收稿日期: 2019-01-07

  修回日期: 2019-05-09

  网络出版日期: 2019-06-01

基金资助

国家重点研发计划;国家自然科学基金项目;河南省教育厅自然科学研究项目;教育部长江学者和创新团队发展计划项目

Study on the Effect of Gypsum Finish on the Fire Resistance of Polystyrene Board

  • XU Shui-Jun ,
  • YANG Dai-Lin ,
  • WEI Yue-Bei ,
  • XIE Gao-Tiao
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  • 1. School of Safety Science and Engineering,Henan Polytechnic University,Jiaozuo,He’nan 454003,China;
    2. Coal Production Safety Collaborative Innovation Center in Henan Province,Jiaozuo,He’nan 454003,China; 3. Henan Province Key Laboratory of Prevention and Curve of Methane & Fires,Jiaozuo,He’nan 454003,China

Received date: 2019-01-07

  Revised date: 2019-05-09

  Online published: 2019-06-01

摘要

针对聚苯乙烯板受热易分解和耐火性不高的问题,以盐石膏和粉煤灰为基材制作自流平砂浆,在聚苯乙烯板表面涂覆自流平砂浆饰面层,研究饰面层对其热稳定性和耐火性能的影响。结果表明:石膏饰面层在升温过程中可将聚苯乙烯芯材有效地包裹起来,延缓聚苯乙烯芯材板的热分解,涂覆饰面层的聚苯乙烯板的残炭率相比纯聚苯乙烯板增加了 4.3倍,其热释放速率峰值和总热释放量随着饰面层厚度的增加而降低;聚苯乙烯板的升温速率随着饰面层厚度的增加而降低,达到耐火极限的时间随厚度的增加而延长;在整个升温过程中,厚度 2 mm、3 mm和 4 mm饰面层的硬度值
损失率分别为 50.82%、41.98%和 37.52%,表面硬度值损失率随着饰面层厚度增加而降低。

本文引用格式

于水军 , 杨岱霖 , 魏月贝 , 谢高超 . 石膏饰面层对聚苯乙烯板耐火性能影响[J]. 涂料工业, 2019 , 49(6) : 29 -34 . DOI: 10.12020/j.issn.0253-4312.2019.6.29

Abstract

In order to solve the problem of easy to decompose and low fire resistance ofpolystyrene boards,a self-leveling mortar was prepared by using salt gypsum and fly ash andapplied on the substrates,and the effects of the self-leveling mortar finish on the thermal stabilityand fire resistance of the polystyrene board were studied. The results showed that the gypsumfinish layer could wrap the polystyrene core material well during the heating process,delaying the thermal decomposition of the polystyrene board,and the residual carbon of the polystyreneboard coated with the finish layer was increased by 4.3 times compared with the polystyrenesheet alone. The peak heat release rate and total heat release decreased as the thickness of thefinish layer increased;the temperature rising rate of the polystyrene board decreased with theincrease of the thickness of the finish layer,and the time to reach the fire endurance was prolonged with the increase of the thickness;during the whole heating process,the thickness reduction of the finish layer of 2 mm,3 mm and 4 mm were 50.82%,41.98%and 37.52%,respectively . The surface hardness decreased as the thickness of the finish layer increased.

参考文献

[1]王正洲,孙皓宇,胡立飞.可发性聚苯乙烯无卤阻燃泡沫材料制备及性能[J].建筑材料学报, 2016, (2):280-284
[2]KILIARIS P,PAPASPYRIDES C D.Polymerlayered silicate(clay)nanocomposites:an overview of flame retardancy[J].Progress in Polymer Science, 2010, 35(7):902-958
[3]李玉臻,汪磊 .二硫化铁(FeS2)纳米颗粒对聚苯乙烯(PS)热稳定性和燃烧性能的影响 [J].火灾科学, 2013(2): 88-93.
[4]KHANAL S,ZHANG W,AHMED S,et al. Effects of intu. mescent flame retardant system consisting of trisisocyanurate and ammonium polyphosphate onthe flame retardant properties of high-density polyethylenecomposites[J].[J].Composites Part A:Applied Science and Manufacturing, 2018, 112:444-451
[5]HAMDANI-DEVARENNES S,EL HAGE R,DUMAZERT L,et al. Water-based flame retardant coating using nano-boehmite for expanded polystyrenefoam[J].[J].Progress in Organic Coatings, 2016, 99:32-46
[6]于水军,陈亮,魏月贝.无机包覆聚苯乙烯泡沫板烟气产生规律研究[J].安全与环境学报, 2018, (2):523-526
[7]YEWMC,RAMLI SULONG N H,YEW M K,et al. Influ. ences of flame-retardant fillers on fire protection and me.chanical properties of intumescent coatings[J].[J].Progress inOrganic Coatings, 2015, 78:59-66
[8]梁光明,罗荡荡.氢氧化铝在膨胀型钢结构防火涂料中的应用研究[J].涂料工业, 2017, 47(12):70-73
[9]许晓晴,王爽,田宏,等.无机阻燃剂对防火涂料性能的影响[J].消防科学与技术, 2017, 36(12):1706-1709
[10]FANG Y,CUI P,DING Z,et al. Properties of a magnesium phosphate cement-based fire-retardant coating containingglass fiber or glass fiber powder[J]. Construction and Build.[J].ing Materials, 2018, 162:553-560
[11]YANG L,ZHANG Y,YAN Y. Utilization of original phos.phogypsum as raw material for the preparation of self-level.ing mortar[J].[J].Journal of Cleaner Production, 2016, 127:204-213
[12]于水军,魏月贝,杨岱霖.基于正交试验的粉煤灰石膏基自流平砂浆性能研究[J].硅酸盐通报, 2018, (10):3217-3222
[13]CHEN H,WANG J,NI A,et al. Effect of novel intumescent flame retardant on mechanical and flame retardant proper.ties of continuous glass fibre reinforced polypropylene com.posites[J].[J].Composite Structures, 2018, 203:894-902
[14]张虎,谢亦富,黄佩坚,等.无溶剂生物基聚氨酯刚性自流平地坪涂料的研发[J].涂料工业, 2017, 47(12):53-58
[15]LU Y,WU C,XU S. Mechanical,thermal and flame retar. dant properties of magnesium hydroxide filled polycomposites:the effect of filler shape[J]. Compos.[J].ites Part A:Applied Science and Manufacturing, 2018, 113:1-11
[16]TANG H,ZHOU X,LIU X. Effect of magnesium hydroxideon the flame retardant properties of unsaturated polyesterresin[J].[J].Procedia Engineering, 2013, 52:336-341
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