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纤维素纳米晶改性光固化水性聚氨酯丙烯酸酯及其性能研究

  • 雷德华 ,
  • 崔艳艳 ,
  • 刘晓暄 ,
  • 苏嘉辉 ,
  • 李华林 ,
  • 叶祖山
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  • 广东省光固化先进材料工程技术研究中心,广东工业大学材料与能源学院,广州 510006

收稿日期: 2018-12-07

  修回日期: 2019-03-07

  网络出版日期: 2019-05-01

基金资助

国家自然科学基金;中国博士后科学基金;广东省重大科技专项;广东省重大科技专项;广东省科技计划项目

Study on Properties of Cellulose Nanocrystals Modified UV-Curable Waterborne Polyurethane Acrylate

  • LEI De-Hua ,
  • CUI Yan-Yan ,
  • LIU Xiao-Xuan ,
  • SU Jia-Hui ,
  • LI Hua-Lin ,
  • XIE Zu-Shan
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  • Guangdong Province Engineering Research Center of UV-curing Advanced Materials,School of Material and Energy Engineering,Guangdong University of Technology,Guangzhou 510006,China

Received date: 2018-12-07

  Revised date: 2019-03-07

  Online published: 2019-05-01

摘要

以纤维素纳米晶( CNC)作为添加物,对紫外光固化水性聚氨酯丙烯酸酯( UV-WPUA)进行共混改性。通过实时红外、转矩流变仪、紫外 -可见光分光光度计、扫描电子显微镜( SEM)、电子万能试验机等表征手段探究了 CNC的添加量对复合树脂及其光固化涂层的性能影响。结果表明:当 CNC的添加量为 2%时, CNC颗粒在复合树脂中分散性良好,复合涂层的可见光透过率大于 85%,铅笔硬度 3H,附着力 0级,拉伸强度 9. 8 MPa,复合涂层的综合性能最好。

本文引用格式

雷德华 , 崔艳艳 , 刘晓暄 , 苏嘉辉 , 李华林 , 叶祖山 . 纤维素纳米晶改性光固化水性聚氨酯丙烯酸酯及其性能研究[J]. 涂料工业, 2019 , 49(5) : 1 -7 . DOI: 10.12020/j.issn.0253-4312.2019.5.1

Abstract

The title cellulose nanocrystals(CNC)was used as additive to modify the UV-curable waterborne polyurethane acrylate(UV-WPUA)resin by blending. The properties of theblended resin and the cured coatings were characterized by real-time fourier transform infraredspectroscopy(real-time FT-IR), torque rheometer,UV-Vis spectrophotometer,scanning electron microscope(SEM)and electronic universal testing machine. The results showed thatwhen the incorporation level of CNC was 2 wt%,it was dispersed well in the blended resin andthe comprehensive properties of the coatings was the optimal:transmittance in visible range was higherthan 85%,pencil hardness 3H,adhesion 0 grade,tensile strength 9.8 MPa.

参考文献

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