工艺技术

铝合金表面GPTMS硅烷膜的制备及耐蚀性能研究

  • 周洋
展开
  • 1.华电电力科学研究院,有限公司,山东司,济南 250002;2.合肥工业大学化学工程学院,合肥 230009
周洋(1987—),男,硕士,研究方向为金属表面处理。

收稿日期: 2019-06-26

  修回日期: 2019-11-02

  网络出版日期: 2020-02-01

Preparation of(γ-glycidoxypropyl)Trimethoxy Silane Film on Aluminum Alloy Surface and Study on Its Corrosion Resistance

  • ZHOU Yang
Expand
  • 1. Shandong Branch of Huadian Electric Power Research Institute Co. Ltd,Jinan 250002,China;
    2. School of Chemical Engineering,Hefei University of Technology,Hefei 230009,China

Received date: 2019-06-26

  Revised date: 2019-11-02

  Online published: 2020-02-01

摘要

为提高铝合金耐腐蚀力,运用正交试验法研究在铝合金表面制备 γ-(2,3-环氧丙氧)丙基三甲氧基硅烷(GPTMS)自组装膜最佳工艺条件,利用极化曲线和扫描电子显微镜研究该硅烷膜在铝合金表面的耐腐蚀性能。研究表明:最佳工艺条件为 100 mL溶液中, pH=4. 5,V(GPTMS)∶V(EtOH)∶V(H2O)= 2∶7∶91,T1(水解温度)=25 ℃,t1(水解时间)=7 h,t2(浸涂时间)=10 min,t3(固化时间)=90 min,T2(固化温度)=120 ℃,该工艺条件下制备的硅烷膜具有优异的耐腐蚀性能。

本文引用格式

周洋 . 铝合金表面GPTMS硅烷膜的制备及耐蚀性能研究[J]. 涂料工业, 2020 , 50(1) : 20 -25 . DOI: 10.12020/j.issn.0253-4312.2020.1.20

Abstract

The optimal process conditions for preparation of self-assembly film were designed by orthogonal experiment with γ-glycidoxypropyl trimethoxy silane(GPTMS)and the silane films were prepared on the surface of aluminum alloy to improve its corrosion resistance.The corrosion resistance of the optimal films on the surface of aluminum alloy was studied by polarization curveand scanning electron microscope(SEM). The results indicated that the optimal process conditions were as follows:the pH value of the solution 4. 5,V(GPTMS)∶V(EtOH]∶ V(H2O)=2∶7∶91,T1(hydrolysis temperature)=25 ℃,t 1(hydrolysis time)=7 h,t 2(immersion time)=10 min,t 3(curingtime) = 90 min,T 2(curing temperature)=120 ℃,The silane films on aluminum alloy in this condition provided good corrosion resistance.

参考文献

[1]WANG F,LUO H,WANG Q,et al.Preparation ofsuperhydrophobicpolymericfilm onaluminumplatesby electro-chemical polymerization[J].Molecules, 2009, 14(11):4737-4746
[2]HU J M,LIU L,ZHANG J Q,et al.Effects of electrodeposition potential on the corrosion properties ofbis-l,2-[triethoxysilyl] ethane films on aluminum alloy[J].Electrochimica Acta,2006,51(19)3944-3949.
[3]余美琼.铝及铝合金表面处理技新进展[J].化学工程与装备, 2008, (6):84-95
[4]胡吉明,刘倞,张金涛,等 .铝合金表面 BTSE硅烷化处理研究[J].金属学报,2004,40(11)1189-1194.
[5]何俊,于萍,罗运柏.铜缓蚀剂究现状与进展[J].材料保护, 2006, 39(4):42-47
[6]FANHQ,LI S Y,SHI Z C,et al.Studies of the conversion coatings formed by combined use of lanthanum salt andbenzotriazole on commercial brass[J].Anti-Corrosion Methods and Materials, 2012, 59(1):32-38
[7] SINKO J.Challenges of chromate inhibitor pigments replace-ment in organic coating[J]. Progress in Organic Coatings, 2001,42(3-4)267-282.
[8]DEFLORIAN FOSSI S,FAMBRI L,et al.Study of thecorrosion behaviour of phosphatized and painted industrialwater heaters[J].Progress in Organic Coatings, 2001, 42(1-2):65-74
[9]TANGN,VAN OOIJ W J,GORECKI G.Comparative EISstudy of pretreatment performance in coated metalsprog[J].Progress in Organic Coatings, 1997, 30(4):255-263
[10]CABRAL A M,MONTEMOR M F,FERREIRA M G S,et al.The corrosion resistance of hot dip galvanised steel andAA2024-T3 pre-treated with bis -[triethoxysilylpropyl] tetra-sulfide solutions doped with Ce(NO3)3[J].Corrosion Science, 2006, 48(11):3740-3758
[11]PROSEK T,THIERRY D.A model for the release of chromate from organic coatings[J].Progress in Organic Coatings, 2004, 49(3):209-217
[12]赵启亮,张俊良,钟庆东,等.镀锌钢板硅烷钝化膜的制备及其电化学性能[J].腐蚀与防护, 2017, 38(1):17-20
[13]赵然,高欣宝,鲁彦玲,等.反应浓度对铝镁合金粉表面硅烷膜的形成及热性能的影响[J].功能材料, 2017, 48(7):173-177
[14]鲁道荣,周洋,桂宏亮.热镀锌钢表面复合纳米材料硅烷膜的耐蚀性能[J].材料热处理学报, 2013, 34(12):166-170
[15]陈明安,谢玄,戚海英,等.铝合金表面双 -γ-三乙氧基硅丙基四硫化物薄膜的特性[J].物理化学学报, 2006, 22(8):1025-1029
[16]PARKHIL R L,KNOBBE E T,DONLEY M S. Applicationand evaluation of environ mentally compliant spray-coated ormosil films as corrosion resistant treatments for aluminum.[J].-T3[J]. Progress in Organic, 2024, Coatings,2001,41::261-265.-
[17]OSBORNE H J,BOHOWIAK K Y,TAYLOR S R,et al. Testing and evaluation of nonchromated coating systems foraerospace applications[J].[J].Progress in Organic Coatings, 2001, 41:217-225
[18]BERWAGEN G P,TALLMAN D E. Choice and measure-ment of crucial aircraft coatings system properties[J].[J].Progress in Organic Coatings, 2001, 41:201-216
文章导航

/