使用含有脂肪长链柔性链段的月桂二酸(DDDA)及1,4-丁二醇二缩水甘油醚(BDDGE),对环氧树脂(E-51)进行降黏增韧改性,再与甲基丙烯酸酐(MA2O)酯化,制备了低黏度柔性UV固化环氧丙烯酸酯。研究了不同反应条件及BDDGE用量对改性环氧丙烯酸酯及涂膜性能的影响,得出了适宜的反应条件。通过红外光谱和热重分析对产物及涂膜进行了测试,结果表明:改性环氧丙烯酸树脂的柔韧性明显增加,涂膜铅笔硬度为3H,附着力为1级,柔韧性1 mm,耐冲击性50 cm,涂膜耐水性较优,但耐热性稍有下降。
Low-Viscosity UV curable epoxy acrylate resin with excellent flexibility was synthesized by the esterification reaction of the epoxy resin that was modified by the viscosity reducing and toughening of the dodecanedioic acid (DDDA),1,4-butanediol diglycidyl ether (BDDGE) containing long aliphatic flexible chain segments and the methacrylic anhydride (MA2O).The influence of the different reaction conditions and the dosage of BDDGE on the synthesis of the modified epoxy acrylate was studied, and the optimum reaction conditions were given. The structure of the products and heat resistance of the films were characterized by Fourier transform infrared spectroscopy and thermogravimetric analysis.The results showed that the modified epoxy acrylate resin toughness was significantly increased, the film pencil hardness was 3H, adhesion level was 1,the flexibility was 1 mm,the resistance impact strength reached 50 cm, moreover, it had good water resistance whereas indicated a slight decrease in heat resistance.
[1]DECKER C.Kinetic study and new applications of UV radiation curing[J].Macromolecular Rapid Communications, 2002, 23(18):1067-1093
[2]YAGCI Y, JOCKUSCH S, TURRO N J.Photoinitiated polymerization: advances, challenges, and opportunities[J].Macromolecules, 2010, 43(15):6245-6260
[3]CHATTOPADHYAY D K, PANDA S S, RAJU K V S N.Thermal and mechanical properties of epoxy acrylate/methacrylates UV cured coatings[J].Progress in Organic Coatings, 2005, 54(1):10-19
[4]LIU F G, MIAO L Q, WANG Y, et al. Green fabrication of ultraviolet curable epoxy acrylate-silica hybrid coatings[J]. Progress in Organic Coatings,.[J].,, 2017, 109::38-44.-
[5]MANSOUR S H, MOSTAFA N, ABD-EL-MESSIEH L.Electrical and positron annihilation study on epoxy and epoxy acrylate composites[J].European Polymer Journal, 2007, 43(11):4770-4782
[6]SHEN L, LI Y W, ZHENG J, et al. Modified epoxy acrylate resin for photocurable temporary protective coatings[J]. Progress in Organic Coatings,.[J].,, 2015, 89::17-25.-
[7]YAN R, YANG D L, ZHANG N N, et al. Performance of UV curable lignin based epoxy acrylate coatings[J]. Progress in Organic Coatings,.[J].,, 2018, 116::83-89.-
[8]王晓丽,刘俊龙,孙祥山, 等.有机二元酸改性环氧丙烯酸酯及其光固化膜性能的研究[J].大连轻工业学院学报, 2007, (3):237-240
[9]韦星船,杨前程,邓妮, 等.固化水性环氧衣康酸树脂的合成及性能研究[J].涂料工业, 2016, 46(1):32-37
[10]WANG H X, BU X W, HUANG Z X, et al.Synthesis of methacrylic anhydride by batch reactive distillation: reaction kinetics and process[J].Industrial & engineering chemistry research, 2014, 53(44):17317-17324
[11]黄笔武,王晓峰.光敏预聚物丁二醇二缩水甘油醚二丙烯酸酯的合成和性能测试[J].南昌大学学报(理科版), 2008, (3):243-246
[12]杨传景.紫外光固化环氧丙烯酸酯体系的增韧研究[D].广州:华南理工大学,2011.
[13]MATEJKA L, LOVY J,POKORNY S, et al.Curing epoxy resins with anhydrides model reactions and reaction mechanism[J].Journal of polymer science part a polymer chemistry, 1983, 21(10):2873-2885